(Z)-1-Chloro-1-[2-(2-nitrophenyl)hydrazinylidene]propan-2-one
نویسندگان
چکیده
The title mol-ecule, C9H8ClN3O3, lies on a mirror plane. Intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonds occur. One of the nitro O atoms is disordered (site occupancy ratio = 0.40:0.10).
منابع مشابه
1-Chloro-1-[(4-nitrophenyl)hydrazinylidene]propan-2-one
The non-H atoms of the title compound, C(9)H(8)ClN(3)O(3), lie approximately on a plane (r.m.s. deviation = 0.111 Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H⋯O(carbon-yl) hydrogen bond, forming a chain running along [101].
متن کامل1-Chloro-1-[(4-methoxyphenyl)hydrazinylidene]propan-2-one
The non-H atoms of the title compound, C(10)H(11)ClN(2)O(2), lie nearly on a plane (r.m.s. deviation = 0.150 Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H⋯O(carbon-yl) hydrogen bond, forming a chain running along [201].
متن کامل1-Chloro-1-[(4-chlorophenyl)hydrazinylidene]propan-2-one
The non-H atoms of the title compound, C(9)H(8)Cl(2)N(2)O, lie nearly on a plane (r.m.s. deviation = 0.110 Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H⋯O(carbon-yl) hydrogen bond, forming a chain running along [100].
متن کامل1-Chloro-1-[(4-methylphenyl)hydrazinylidene]propan-2-one
The asymmetric unit of the title compound, C(10)H(11)ClN(2)O, contains two mol-ecules. The non-H atoms of each mol-ecule lie approximately on a plane (r.m.s. deviations = 0.062 and 0.110 Å), and the C=N double bond has a Z-configuration in both independent mol-ecules. In the crystal, adjacent mol-ecules are linked by N-H⋯O(carbon-yl) hydrogen bonds, forming chains running along [100].
متن کامل(Z)-Ethyl 2-chloro-2-[2-(4-methylphenyl)hydrazinylidene]acetate
The mol-ecule of the title compound, C11H13ClN2O2, is approximately planar (r.m.s. deviation = 0.099 Å for non-H atoms) and adopts a Z conformation about the C=N double bond. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds to the same O-atom acceptor, forming zigzag chains propagating along [010]. These inter-actions give rise to R2(1)(6) loops.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013